At the turn of the century, several phenomena connected with the structure of atoms and inexplicable in terms of classical physics were discovered. The first indication that atoms had some structure came from the discovery of X-rays; a new radiation which rapidly found its now Well known application in medicine. X-rays, however, are not the only radiation emitted by atoms. Soon after their discovery, other kinds of radiation were discovered which are emitted by the atoms of so-called radioactive substances. The phenomenon of radioactivity gave definite proof of the composite nature of atoms, showing that the atoms of radioactive substances not only emit various types of radiation, but also transform themselves into atoms of completely different substances.
Besides being objects of intense study, these phenomena were also used, in most ingenious ways, as new tools to probe deeper into matter than had ever been possible before. Thus Max von Laue used X-rays to study the arrangements of atoms in crystals, and Ernest Rutherford realized that the so-called alpha particles emanating from radioactive substances were high-speed projectiles of subatomic size which could be used to explore the interior of the atom. They could be fired at atoms, and from the way they were deflected one could draw conclusions about the atoms’ structure.
When Rutherford bombarded atoms with these alpha particles, he obtained sensational and totally unexpected results. Far from being the hard and solid particles they were believed to be since antiquity, the atoms turned out to consist of vast regions of space in which extremely small particles—the electrons—moved around the nucleus, bound to it by electric forces. It is not easy to get a feeling for the order of magnitude of atoms, so far is it removed from our macroscopic scale. The diameter of an atom is about one hundred millionth of a centimetre. In order to visualize this diminutive size, imagine an orange blown up to the size of the Earth. The atoms of the orange will then have the size of cherries. Myriads of cherries, tightly packed into a globe of the size of the Earth—that’s a magnified picture of the atoms in an orange.
An atom, therefore, is extremely small compared to macroscopic objects, but it is huge compared to the nucleus in its centre. In our picture of cherry-sized atoms, the nucleus of an atom will be so small that we will not be able to see it. If we blew up the atom to the size of a football, or even to room size, the nucleus would still be too small to be seen by the naked eye. To see the nucleus, we would have to blow up the atom to the size of the biggest dome in the world, the dome of St Peter’s Cathedral in Rome. In an atom of that size, the nucleus would have the size of a grain of salt! A grain of salt in the middle of the dome of St Peter’s, and specks of dust whirling around it in the vast space of the dome—this is how we can picture the nucleus and electrons of an atom.
Soon after the emergence of this ‘planetary’ model of the atom, it was discovered that the number of electrons in the atoms of an element determine the element’s chemical properties, and today we know that the whole periodic table of elements can be built up by successively adding protons and neutrons to the nucleus of the lightest atom—hydrogen*—and the corresponding number of electrons to its atomic ‘shell’. The interactions between the atoms give rise to the various chemical processes, so that all of chemistry can now in principle be understood on the basis of the laws of atomic physics.
These laws, however, were not easy to recognize. They were discovered in the 1920s by an international group of physicists including Niels Bohr from Denmark, Louis De Broglie from France, Erwin Schrödinger and Wolfgang Pauli from Austria, Werner Heisenberg from Germany, and Paul Dirac from England. These men joined their forces across all national borders and shaped one of the most exciting periods in modern science, which brought them, for the first time, into contact with the strange and unexpected reality of the subatomic world. Every time the physicists asked nature a question in an atomic experiment, nature answered with a paradox, and the more they tried to clarify the situation, the sharper the paradoxes became. It took them a long time to accept the fact that these paradoxes belong to the intrinsic structure of atomic physics, and to realize that they arise whenever one attempts to describe atomic events in the traditional terms of physics. Once this was perceived, the physicists began to learn to ask the right questions and to avoid contradictions. In the words of Heisenberg, ‘they somehow got into the spirit of the quantum theory’, and finally they found the precise and consistent mathematical formulation of this theory.
The concepts of quantum theory were not easy to accept even after their mathematical formulation had been completed. Their effect on the physicists’ imagination was truly shattering. Rutherford’s experiments had shown that atoms, instead of being hard and indestructible, consisted of vast regions of space in which extremely small particles moved, and now quantum theory made it clear that even these particles were nothing like the solid objects of classical physics. The subatomic units of matter are very abstract entities which have a dual aspect. Depending on how we look at them, they appear sometimes as particles, sometimes as waves; and this dual nature is also exhibited by light which can take the form of electromagnetic waves or of particles.
This property of matter and of light is very strange. It seems impossible to accept that something can be, at the same time, a particle—i.e. an entity confined to a very small volume—and a wave, which is spread out over a large region of space. This contradiction gave rise to most of the koan-like paradoxes which finally led to the formulation of quantum theory. The whole development started when Max Planck discovered that the energy of heat radiation is not emitted continuously, but appears in the form of ‘energy packets’. Einstein called these energy packets ‘quanta’ and recognized them as a fundamental aspect of nature. He was bold enough to postulate that light and every other form of electromagnetic radiation can appear not only as electromagnetic waves, but also in the form of these quanta. The light quanta, which gave quantum theory its name, have since been accepted as bona fide particles and are now called photons. They are particles of a special kind, however, massless and always travelling with the speed of light.
The apparent contradiction between the particle and the wave picture was solved in a completely unexpected way which called in question the very foundation of the mechanistic world view—the concept of the reality of matter. At the subatomic level, matter does not exist with certainty at definite places, but rather shows ‘tendencies to exist, and atomic events do not occur with certainty at definite times and in definite ways, but rather show ‘tendencies to occur. In the formalism of quantum theory, these tendencies are expressed as probabilities and are associated with mathematical quantities which take the form of waves. This is why particles can be waves at the same time. They are not ‘real’ three-dimensional waves like sound or water waves. They are ‘probability waves’, abstract mathematical quantities with all the characteristic properties of waves which are related to the probabilities of finding the particles at particular points in space and at particular times. All the laws of atomic physics are expressed in terms of these probabilities. We can never predict an atomic event with certainty; we can only say how likely it is to happen.
Quantum theory has thus demolished the classical concepts of solid objects and of strictly deterministic laws of nature. At the subatomic level, the solid material objects of classical physics dissolve into wave-like patterns of probabilities, and these patterns, ultimately, do not represent probabilities of things, but rather probabilities of interconnections. A careful analysis of the process of observation in atomic physics has shown that the subatomic particles have no meaning as isolated entities, but can only be understood as interconnections between the preparation of an experiment and the subsequent measurement. Quantum theory thus reveals a basic oneness of the universe. It shows that we cannot decompose the world into independently existing smallest units. As we penetrate into matter, nature does not show us any isolated ‘basic building blocks’,