The solar spectrum is the band of coloured light seen in the rainbow and, partially, in the dew-drop, but more completely when a ray of sunlight passes through a prism—a piece of glass having a triangular section. The result is, that instead of a spot of white light we have a narrow band of brilliant colours which succeed each other in regular order, from violet at one end through blue, green, and yellow to red at the other. We thus see that light is not a simple and uniform radiation from the sun, but is made up of a large number of separate rays, each of which produces in our eyes the sensation of a distinct colour. Light is now explained as being due to vibrations of ether, that mysterious substance which not only permeates all matter, but which fills space at least as far as the remotest of the visible stars and nebulæ. The exceedingly minute waves or vibrations of the ether produce all the phenomena of heat, light, and colour, as well as those chemical actions to which photography owes its wonderful powers. By ingenious experiments the size and rate of vibration of these waves have been measured, and it is found that they vary considerably, those forming the red light, which is least refracted, having a wave-length of about 1/326000 of an inch, while the violet rays at the other end of the spectrum are only about half that length or 1/630000 of an inch. The rate at which the vibrations succeed each other is from 302 millions of millions per second for the extreme red rays, to 737 millions of millions for those at the violet end of the spectrum. These figures are given to show the wonderful minuteness and rapidity of these heat and light waves on which the whole life of the world, and all our knowledge of other worlds and other suns, directly depends.
But the mere colours of the spectrum are not the most important part of it. Very early in the nineteenth century a close examination showed that it was everywhere crossed by black lines of various thicknesses, sometimes single, sometimes grouped together. Many observers studied them and made accurate drawings or maps showing their positions and thicknesses, and by combining several prisms, so that the beam of sunlight had to pass through them successively, a spectrum could be produced several feet long, and more than 3000 of these dark lines were counted in it. But what they were and how they were caused remained a mystery, till, in the year 1860, the German physicist Kirchhoff discovered the secret and gave to chemists and astronomers a new and quite unexpected engine of research.
It had already been observed that the chemical elements and various compounds, when heated to incandescence, produced spectra consisting of coloured lines or bands which were constant for each element, so that the elements could at once be recognised by their characteristic spectra; and it had also been noticed that some of these bands, especially the yellow band produced by sodium, corresponded in position with certain black lines in the solar spectrum. Kirchhoff's discovery consisted in showing that, when the light from an incandescent body passes through the same substance in a state of vapour or gas, so much of the light is absorbed that the coloured lines or bands become black. The mystery of more than half a century was thus solved; and the thousands of black lines in the solar spectrum were shown to be caused by the light from the incandescent matter of the sun's surface passing through the heated gases or vapours immediately above it, and thereby having the bright coloured lines of their spectra changed, by absorption, to comparative blackness.
Chemists and physicists immediately set to work examining the spectra of the elements, fixing the position of the several coloured lines or bands by accurate measurement, and comparing them with the dark lines of the solar spectrum. The results were in the highest degree satisfactory. In a large proportion of the elements the coloured bands corresponded exactly with a group of dark lines in the spectrum of the sun, in which, therefore, the same terrestrial elements were proved to exist. Among the elements first detected in this manner were hydrogen, sodium, iron, copper, magnesium, zinc, calcium, and many others. Nearly forty of the elements have now been found in the sun, and it seems highly probable that all our elements really exist there, but as some are very rare and are present in very minute quantities they cannot be detected. Some of the dark lines in the sun were found not to correspond to any known element, and as this was thought to indicate an element peculiar to the sun it was named Helium; but quite recently it has been discovered in a rare mineral. Many of the elements are represented by a great number of lines, others by very few. Thus iron has more than 2000, while lead and potassium have only one each.
The value of the spectroscope both to the chemist in discovering new elements and to the astronomer in determining the constitution of the heavenly bodies, is so great, that it became of the highest importance to have the position of all the dark lines in the solar spectrum, as well as the bright lines of all the elements, determined with extreme accuracy, so as to be able to make exact comparisons between different spectra. At first this was done by means of very large-scale drawings showing the exact position of every dark or bright line. But this was found to be both inconvenient and not sufficiently exact; and it was therefore agreed to adopt the natural scale of the wave-lengths of the different parts of the spectrum, which by means of what are termed diffraction-gratings can now be measured with great accuracy. Diffraction-gratings are formed of a polished surface of hard metal ruled with excessively fine lines, sometimes as many as 20,000 to an inch. When sunlight falls upon one of these gratings it is reflected, and by interference of the rays from the spaces between the fine grooves, it is spread out into a beautiful and well-defined spectrum, which, when the lines are very close, is several yards in length. In these diffraction spectra many dark lines are seen which can be shown in no other way, and they also give a spectrum which is far more uniform than that produced by glass prisms in which minute differences in the composition of the glass cause some rays to be refracted more and others less than the normal amount.
The spectra produced by diffraction-gratings are double; that is, they are spread out on both sides of the central line of the ray which remains white, and the several coloured or dark lines are so clearly defined that they can be thrown on a screen at a considerable distance, giving a great length to the spectrum. The data for obtaining the wave-lengths are the distance apart of the lines, the distance of the screen, and the distance apart of the first pair of dark lines on each side of the central bright line. All these can be measured with extreme accuracy by means of telescopes with micrometers and other contrivances, and the result is an accuracy of determination of wave-lengths which can probably not be equalled in any other kind of measurement.
As the wave-lengths are so excessively minute, it has been found convenient to fix upon a still smaller unit of measurement, and as the millimetre is the smallest unit of the metric system, the ten-millionth of a millimetre (technically termed 'tenth meter') is the unit adopted for the measurement of wave-lengths, which is equal to about the 250 millionth of an inch. Thus the wave-lengths of the red and blue lines characteristic of hydrogen are 6563.07 and 4861.51 respectively. This excessively minute scale of wave-lengths, once determined by the most refined measurement, is of very great importance. Having the wave-lengths of any two lines of a spectrum so determined, the space between them can be laid down on a diagram of any length, and all the lines that occur in any other spectrum between these two lines can be marked in their exact relative positions. Now, as the visible spectrum consists of about 300,000 rays of light, each of different wave-lengths and therefore of different refrangibilities, if it is laid down on such a scale as to be of a length of 3000 inches (250 feet), each wave-length will be 1/100 of an inch long, a space easily visible by the naked eye.
The possession of an instrument of such wonderful delicacy, and with powers which enable it to penetrate into the inner constitution of the remotest orbs of space, rendered it possible, within the next quarter of a century, to establish what is practically a new science—Astrophysics—often popularly termed the New Astronomy.