Natural History Collections in the Science of the 21st Century. Группа авторов. Читать онлайн. Newlib. NEWLIB.NET

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Издательство: John Wiley & Sons Limited
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isbn: 9781119882220
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to the Louis XIV blue diamond was based on the concept of critical angle (θ2), which is related to the angle of total reflection itself as a function of the diamond’s refractive index, worth 2.42 on average (i.e. θ2 ~ 26°, Figure 3.4(a)). The light path (ray 1 in Figure 3.4(b)) passed through the diamond given its angle of incidence (θ1) zero with respect to the perpendicular angle of the diamond table. It passed through the diamond/gold diopter and returned the image of the underlying gold setting. The path (radius 2 in Figure 3.4(b)) corresponds to the incidence of light on the slightly off-center diamond (θ1). Again, the angle of incidence was less than the critical angle and the light was still reflected by the gold. As for the third path (ray 3 in Figure 3.4(b)), it corresponded to the case where the light arrived on the facets of the pavilion with an angle greater than the critical angle: the light was then reflected in the diamond which increased its absorption and, consequently, the color perceived by the observer in return. Clearly, Louis XIV’s gem cutter had mastered, knowingly or not, the founding concepts of linear optics published by Descartes (1596–1650) in La Dioptrique (Descartes 1637). The computer simulation of the Louis XIV blue diamond gave a diamond with blue hues centered on a sapphire blue. In the 17th century, the term “violet” was used to designate both dark blue and the current violet. As far as the Louis XIV diamond is concerned, it is the “sapphire blue variant” of “violet” that is the correct color for this diamond.

      This heliocentric vision contrasted with the Platonic dogmas then recognized by the Church in which the Sun was supposed to orbit the Earth. It was not until 1755 that the Vatican admitted this “modernist” version of the mechanics of the solar system. Clearly, Louis XIV did not wait for the papacy: Descartes had already been published in his post-humous opus The World (originally dated 1633; Descartes 1664) where he took up the cause of Galileo and his assertions on heliocentrism. Through his “modernist” vision, Louis XIV asserted his Gallicanism above all against the ultramontanes (and other “Vatican-ultras” in France like the Compagnie du Saint-Sacrement (Company of the Blessed Sacrament) who were more subservient to the Vatican than to the power of the young sovereign, which the latter wanted to be absolute.

      As for the Grand Saphir (Figure 3.2), it was also set in gold as the royal inventories indicate. We have been able to undertake a gemological study since the original gem has been preserved today: it constitutes, along with the Hortensia diamond of the Louvre Museum, the only two remains of the fabulous gem acquisitions by Louis XIV that have been kept intact to date. UV-vis-NIR spectroscopic analysis (Farges et al. 2015) of this gem shows that the sapphire originated in Sri Lanka. We can even see growth zones and inclusions that allow us to conclude that this sapphire has not been heated to accentuate its blue color. The zonations show that the original crystal was much larger, but these extra volumes must have been less transparent and were removed by recutting.

      In the end, it is astonishing that the two blue gems of Louis XIV ended up in the Muséum national d’Histoire naturelle: one intact and the other in the form of a lead cast, the original of which has definitely disappeared. To a certain extent, this long-ignored lead cast has become the “original” and its precise study shows that its creator – still unknown at this stage – wanted to keep the trace of exceptional expertise by making this historical replica. My very recent observation (end of 2018) of the surface of this lead cast would seem to indicate that the date “1806” is inscribed on it. This type of lead casting is usually done prior to a sale or re-cut so that the gem cutter can keep track of his excellence for future customers. If this hypothesis is true, this information would indicate the date of the recutting of the Louis XIV blue diamond, which corresponds exactly to the time window between the theft of the French diamond in Paris and the first appearance in London (1792–1812) of what would later be named the Hope diamond, now kept at the Smithsonian.

      Figure 3.4. Optical principles of a generic faceted diamond explaining definition and measurement. © F. Farges/MNHN

      COMMENT ON FIGURE 3.4.– (a) Measurement of the critical angle, θ2, for an air (1)/gem (2) interface (also called a diopter). For a light incidence (θ1) smaller than this angle, the diamond will behave like a transparent diopter. Otherwise, the facets of the gem will behave like mirrors: the light will be more absorbed and the color will be perceived as more intense (darker); (b) optical principles for three typical light paths; (c) computer simulation of the Louis XIV blue diamond on the basis of the MNHN inv. 50.165 cast and the color of the Hope diamond and then placed in a model of a setting according to the 1691 inventory.

      Bapst, G. (1889). Histoire des Joyaux de la Couronne de France. Hachette, Paris.

      Descartes, R. (1633). Traité du monde