Natural History Collections in the Science of the 21st Century. Группа авторов. Читать онлайн. Newlib. NEWLIB.NET

Автор: Группа авторов
Издательство: John Wiley & Sons Limited
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Жанр произведения: Биология
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isbn: 9781119882220
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the gem was not found amongst the few remaining gems. On the other hand, the sapphire was found shortly afterward, according to an inventory from December 1792 (Farges et al. 2015). It was deposited at the Hôtel de la Monnaie where it was recovered in 1796 by Daubenton (1716–1799), then a professor at the Muséum. Indeed, the 1789 inventory of the Crown Jewels described the item as a “sapphire piece” because the mineralogist Romé de l’Isle (1736–1790) published – in his Essai de Cristallographie (1772) – that the gem was, according to his studies, a sapphire crystal (an erroneous conclusion as the object was definitively faceted by humans, i.e. a gem).

      Figure 3.2. Gems and models. © F. Farges/MNHN

      COMMENT ON FIGURE 3.2.– (a) Louis XIV’s Grand Saphir (MNHN inv. A.67); (b) ceramic model no. 71 by Romé de l’Isle (circa 1772) representing the Grand Saphir as a natural crystal of “adamantine spar” (corundum); (c) rhinestone model of the Ruspoli sapphire also found in the MNHN collections (inv. 50.167) and given by the same Parisian gem cutter as the model of the blue diamond (see Figure 3.1(a)): a certain M. Achard. The scale is 1 cm.

      For its part, Louis XIV’s Grand Saphir remains strangely absent from the MNHN’s brand image, even though it is certainly the most precious piece in its collections: for example, consider the popularity of the Hope diamond, the “muse” of the Smithsonian Institution in Washington and, more generally, of the Americans who recognize in this blue diamond no less than their own Mona Lisa. Indeed, some semi-confidential gossip in the jewelry world has long suspected the Hope diamond of being Louis XIV’s blue diamond, cut by thieves or their collectors. Without proof, the story will remain as such. France quickly forgot its masterpiece since no painting of this French jewel is known. Until 2007 that is, when we found – in the collections of the Muséum national d’Histoire naturelle – the only cast of this gem stolen in 1792 (Figure 3.1(a)).

      The first investigation consisted of deciding between the two opponents claiming to be the representation of the stolen French Blue diamond. On the one hand, we had the Russian clan which, through the Terestchenko diamond of 42.92 carats, claimed prestigious royal paternity by its ovoid shape. On the other hand, the American clan had the Hope diamond of 45.52 carats. A laser scan of the lead model was performed to obtain a 3D mesh of thousands of polygons of the lead cast of the French Blue diamond to find the truth of these two hypotheses. Numerical methods such as edge collapse decimation enabled the restoration of the original faceting of the gem. This result, when compared to the two competing representations, was clear: the Terestchenko was too long and not wide enough. The American won hands down (Figure 3.1(d)). The thieves of 1792 thus savagely recut the three main corners of the French triangular diamond to give it the present ovoid shape of the Hope diamond.

      Considerable ab initio calculations of the color of the Hope diamond were undertaken to elucidate the anomaly (Farges et al. 2012). For this purpose, the theoretical dielectric function (𝜓) of a diamond was calculated by considering a doping of its cubic atomic structure with boron atoms, present in trace amounts in the carbon atomic structure of this mineral and supposedly the source of its blue color (Fritsch 1998). We then solved the Bethe–Salpeter equation (Farges et al. 2012) that quantified the interaction between light and this mineral to determine its absorption spectrum between ultraviolet and near-infrared (400–900 nm). In summary, these complex calculations allowed us to reproduce and therefore understand the color anomaly of this diamond. In fact, the Hope diamond was not dark blue as it appeared at first sight, but pale blue! The calculation was able to show that its faceting amplified the pale color of the mineral constituting the Hope diamond to the point where the latter appeared blue (almost black) to us (Figure 3.3).

      Figure 3.3. (a) Results of ab initio calculations on the color of the Hope diamond (dashed line) compared to the experiment (solid line) and photo-realistic simulation of this diamond reproducing the color contrast at the center of the gem (compare with Figure 3.1(a)); (b) photo-realistic simulation of this diamond without its cushion-faceting. Images © F. Farges/MNHN