It is, of course, not necessary, when it is desired to produce the incandescence of a body inclosed in a bulb by means of these currents, that the body should be a conductor, for even a perfect non-conductor may be quite as readily heated. For this purpose it is sufficient to surround a conducting electrode with a non-conducting material, as, for instance, in the bulb described before in Fig. 21, in which a thin incandescent lamp filament is coated with a non-conductor, and supports a button of the same material on the top. At the start the bombardment goes on by inductive action through the non-conductor, until the same is sufficiently heated to become conducting, when the bombardment continues in the ordinary way.
A different arrangement used in some of the bulbs constructed is illustrated in Fig. 23. In this instance a non-conductor m is mounted in a piece of common arc light carbon so as to project some small distance above the latter. The carbon piece is connected to the leading-in wire passing through a glass stem, which is wrapped with several layers of mica. An aluminium tube a is employed as usual for screening. It is so arranged that it reaches very nearly as high as the carbon and only the non-conductor m projects a little above it. The bombardment goes at first against the upper surface of carbon, the lower parts being protected by the aluminium tube. As soon, however, as the non-conductor m is heated it is rendered good conducting, and then it becomes the centre of the bombardment, being most exposed to the same.
I have also constructed during these experiments many such single-wire bulbs with or without internal electrode, in which the radiant matter was projected against, or focused upon, the body to be rendered incandescent. Fig. 24 illustrates one of the bulbs used. It consists of a spherical globe L, provided with a long neck n, on the top, for increasing the action in some cases by the application of an external conducting coating. The globe L is blown out on the bottom into a very small bulb b, which serves to hold it firmly in a socket S of insulating material into which it is cemented. A fine lamp filament f, supported on a wire w, passes through the centre of the globe L. The filament is rendered incandescent in the middle portion, where the bombardment proceeding from the lower inside surface of the globe is most intense. The lower portion of the globe, as far as the socket S reaches, is rendered conducting, either by a tinfoil coating or otherwise, and the external electrode is connected to a terminal of the coil.
The arrangement diagrammatically indicated in Fig. 24 was found to be an inferior one when it was desired to render incandescent a filament or button supported in the centre of the globe, but it was convenient when the object was to excite phosphorescence.
In many experiments in which bodies of a different kind were mounted in the bulb as, for instance, indicated in Fig. 23, some observations of interest were made.
It was found, among other things, that in such cases, no matter where the bombardment began, just as soon as a high temperature was reached there was generally one of the bodies which seemed to take most of the bombardment upon itself, the other, or others, being thereby relieved. This quality appeared to depend principally on the point of fusion, and on the facility with which the body was "evaporated," or, generally speaking, disintegrated—meaning by the latter term not only the throwing off of atoms, but likewise of larger lumps. The observation made was in accordance with generally accepted notions. In a highly exhausted bulb electricity is carried off from the electrode by independent carriers, which are partly the atoms, or molecules, of the residual atmosphere, and partly the atoms, molecules, or lumps thrown off from the electrode. If the electrode is composed of bodies of different character, and if one of these is more easily disintegrated than the others, most of the electricity supplied is carried off from that body, which is then brought to a higher temperature than the others, and this the more, as upon an increase of the temperature the body is still more easily disintegrated.
It seems to me quite probable that a similar process takes place in the bulb even with a homogeneous electrode, and I think it to be the principal cause of the disintegration. There is bound to be some irregularity, even if the surface is highly polished, which, of course, is impossible with most of the refractory bodies employed as electrodes. Assume that a point of the electrode gets hotter, instantly most of the discharge passes through that point, and a minute patch is probably fused and evaporated. It is now possible that in consequence of the violent disintegration the spot attacked sinks in temperature, or that a counter force is created, as in an arc; at any rate, the local tearing off meets with the limitations incident to the experiment, whereupon the same process occurs on another place. To the eye the electrode appears uniformly brilliant, but there are upon it points constantly shifting and wandering around, of a temperature far above the mean, and this materially hastens the process of deterioration. That some such thing occurs, at least when the electrode is at a lower temperature, sufficient experimental evidence can be obtained in the following manner: Exhaust a bulb to a very high degree, so that with a fairly high potential the discharge cannot pass—that is, not a luminous one, for a weak invisible discharge occurs always, in all probability. Now raise slowly and carefully the potential, leaving the primary current on no more than for an instant. At a certain point, two, three, or half a dozen phosphorescent spots will appear on the globe. These places of the glass are evidently more violently bombarded than others, this being due to the unevenly distributed electric density, necessitated, of course, by sharp projections, or, generally speaking, irregularities of the electrode. But the luminous patches are constantly changing in position, which is especially well observable if one manages to produce very few, and this indicates that the configuration of the electrode is rapidly changing.
From experiences of this kind I am led to infer that, in order to be most durable, the refractory button in the bulb should be in the form of a sphere with a highly polished surface. Such a small sphere could be manufactured from a diamond or some other crystal, but a better way would be to fuse, by the employment of extreme degrees of temperature, some oxide—as, for instance, zirconia—into a small drop, and then keep it in the bulb at a temperature somewhat below its point of fusion.
Interesting and useful results can no doubt be reached in the direction of extreme degrees of heat. How can such high temperatures be arrived at? How are the highest degrees of heat reached in nature? By the impact of stars, by high speeds and collisions. In a collision any rate of heat generation may be attained. In a chemical process we are limited. When oxygen and hydrogen combine, they fall, metaphorically speaking, from a definite height. We cannot go very far with a blast, nor by confining heat in a furnace, but in an exhausted bulb we can concentrate any amount of energy upon a minute button. Leaving practicability out of consideration, this, then, would be the means which, in my opinion, would enable us to reach the highest temperature. But a great difficulty when proceeding in this way is encountered, namely, in most cases the body is carried off before it can fuse and form a drop. This difficulty exists principally with an oxide such as zirconia, because it cannot be compressed in so hard a cake that it would not be carried off quickly. I endeavored repeatedly to fuse zirconia, placing it in a cup or arc light carbon as indicated in Fig. 23. It glowed with a most intense light, and the stream of the particles projected out of the carbon cup was of a vivid white: but whether it was compressed in a cake or made into a paste with carbon, it was carried off before it could be fused. The carbon cup containing the zirconia had to be mounted very low in the neck of a large bulb, as the heating