4We have
5
6These commutation relations do not fix the sign of the generator Ki of boosts. We follow in (2.22) the convention adopted by S. Weinberg.
7The minus sign in the last commutation relations reflects the fact that the Lorentz group SO(3, 1) can be considered as the complexification of the rotation group in four dimensions, SO(4). The fact that the commutator of two generators of the boost is given as a linear combination of the generators of rotations is related to the phenomenon of the Thomas precession. From the group theoretic point of view it expresses the fact that, if we perform the sequence of infinitesimal boosts g(−δθ2)g(−δθ1)g(δθ2)g(δθ1) with
8We follow closely the notation of S. Weinberg, Phys. Rev. 133 (1964) B1318.
9We follow again closely the notation of S. Weinberg, Phys. Rev. 133 (1964) B1318 and Phys. Rev. 134 (1964) B882. It is to be kept in mind that, unlike us, S. Weinberg uses the metric gμν = (−1, 1, 1, 1).
10For a more detailed analysis see E. P. Wigner, Ann. Phys. Math. 40 (1939) 149.
11E.P. Wigner, Theoretical Physics (International Atomic Energy Vienna, 1963) p. 59.
12We follow again the notation of S. Weinberg, Phys. Rev. 134 (1964) B882.
Chapter 3
Search for a Relativistic Wave Equation
In this chapter we engage in the search for a relativistic wave equation for a spin zero particle moving in an external potential, reducing to the ordinary Schrödinger equation in the non-relativistic limit. We begin by looking at the case of a free particle. We adhere to the familiar quantum mechanical principles, as long as we can. We shall encounter a number of difficulties which will lead us to eventually abandon the usual probability interpretation.
3.1A relativistic Schrödinger equation
As discussed in Chapter 1, the time evolution of a quantum mechanical state is governed by the equation of motion (ħ = c = 1)
where H is the Hamiltonian operator of the system obtained from the corresponding classical Hamiltonian by representing the canonically conjugate dynamical variables q and p in H(q, p) by operators satisfying canonical commutation relations. In this and the following two sections we consider the case of a free particle. Since in a relativistic theory the relation between the energy of a free particle and its momentum is given by
In the coordinate representation, the canonical commutation relations are as usual realized by
Defining the wave function associated with the state
This equation in turn implies that
where □ denotes the D’Alembert operator. Since this operator is manifestly Lorentz-invariant, covariance of the physical laws demand that under a Lorentz transformation the wave function transforms like a scalar:
This is also implied by Eq. (3.1), since on the space of solutions of the Klein–Gordon equation (3.2) the operator appearing on the left- and right-hand sides of Eq. (3.1) transform in the same way:
Note that in contrast to the non-relativistic case, where the wave function does not transform like a scalar, but rather picks up a phase under Galilei transformations, such a phase is absent in the relativistic case, rendering the covariance of the equation of motion manifest in this case.
The operator appearing on the rhs of Eq. (3.1) is defined in terms of its Taylor expansion:
Hence its eigenfunctions are given by the plane waves
as
The factor 1/2ω(
) has been included in the measure to make it relativistically invariant. In order for where
In order for
In the non-relativistic limit