14 Chapter 13Scheme 13.1 Synthesis of Chalcogran 7.Figure 13.1 Some representative examples of spiroketals.Figure 13.2 Most common spiroketal structures I–V.Scheme 13.2 Synthesis of symmetric 2,7-dialkyl-1,6-dioxaspiro[4.4]nonanes 10...Scheme 13.3 Enantioselective synthesis of 12.Scheme 13.4 Enantioselective synthesis of (E)-18.Scheme 13.5 Synthesis of spiro[4.5]decane 22.Scheme 13.6 Synthesis of γ-Rubromycin 29.Scheme 13.7 Synthesis of spiro[4.6]undecanes 33.Scheme 13.8 Synthesis of 2,7-dialkyl-1,6-dioxaspiro[4.6]undecanes 40.Scheme 13.9 Synthesis of 1,7-dioxaspiro[5.5]undecanes 45a and dioxaspiro[5.6...Scheme 13.10 Synthesis of 2-methyl-1,7-dioxaspiro[5.6]dodecane 52.
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