17 Appendix C: Electrophoresis C.1 Free-Solution Electrophoretic Mobility C.2 Mobility Dependence on Temperature C.3 Transient Regimes References
18 Appendix D: Electroosmosis D.1 Slab and Microchips – Cartesian Coordinates D.2 Capillaries – Cylindrical Coordinates D.3 Zeta Potential References
19 Appendix E: Molecular Diffusion E.1 The Diffusion Equation E.2 The Propagator E.3 Application of Propagators to Bands at Rest E.4 Application of Propagators to Bands in Movement E.5 Bands and Peaks References
20 Appendix F: Poiseuille Counter-flow F.1 Introduction F.2 Velocity Level Contours F.3 Temperature Level Contours F.4 Equalizing and Reference
21 Appendix G: Cyclic On-column Band Compression G.1 Introduction G.2 Effect of Cyclic Band Compression Events on Variance G.3 Number of Theoretical Plates G.4 Number of Theoretical Plates per Unit Time G.5 Height Equivalent of a Theoretical Plate G.6 Resolution G.7 Resolution per Unit Time G.8 Band Capacity G.9 Band Capacity per Unit Time G.10 Detailed Calculation of and References
22 Index
List of Tables
1 Chapter 1Table 1.1 Relative (static) permittivities of liquids at 20 C. Extracted from Wo...Table 1.2 Examples of some LogP values. These are the average values of the mos...
2 Chapter 2Table 2.1 Values of the dimensionless parameters
and of equation 2.21, given ...Table 2.2 Troubleshooting checklist to reduce band dispersion in ESTs.Table 2.3 Procedures to reduce peak width caused by factors other than band disp...Table 2.4 The most appropriate separation modes for each class of analytes when ...3 Chapter 3Table 3.1 Parameters extracted from band/peak 1.Table 3.2 Parameters extracted from band/peak 2.
4 Chapter 5Table 5.1 Performance indicators (PIs) and the procedure used to calculate them ...Table 5.2 Summary of the performance indicators of the open and toroidal layouts...Table 5.3 Summary of the performance indicators in terms of applied voltage (
)....Table 5.4 Summary of the nine performance indicators (PI) without the operationa...Table 5.5 Summary of the performance indicators expressed in terms of the number...5 Chapter 7Table 7.1 List of operational parameters that are affected by temperature and th...Table 7.2 List of acids and bases with their thermodynamic
values, apparent (wo...Table 7.3 List of properties that are important for the efficient performance of...6 Chapter 8Table 8.1 Dependence of the performance indicators on the apparent mobility (
) ...Table 8.2 Examples of non-fluorescent reagents that undergo fluorogenic reaction...7 Appendix GTable G.1 The minimum and maximum values of
, , and as a function of (time Table G.2 Performance indicators of the open layout (open) compared with toroida...List of Illustrations
1 Chapter 1Figure 1.1 Some neighbors of oxygen in the periodic table. The atomic number...Figure 1.2 Schematic representation of chloride anion solvation in water.Figure 1.3 Solvation of the sodium cation in water.Figure 1.4 c–pH diagram of citric acid species in an aqueous