The Rheology Handbook. Thomas Mezger. Читать онлайн. Newlib. NEWLIB.NET

Автор: Thomas Mezger
Издательство: Readbox publishing GmbH
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Жанр произведения: Химия
Год издания: 0
isbn: 9783866305366
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GPa (gigapascal) = 1000 MPa = 1,000,000,000 Pa = 109 Pa

      A previously used unit was [dyne/cm2], then: 1 dyne/cm2 = 0.1 Pa. However, this is not an SI-unit. In Table 4.1 are listed values of shear moduli of various materials.

Table 4.1: Values of G- and E-moduli , and of Poisson’s ratio μ, at the temperature T = +20 °C; own data and from [4.1] [4.2] [4.3] [4.4] [4.5]
MaterialG modulusμE modulus
very soft gel structures (examples: spray coatings, salad dressings)5 to 10 Pa
soft gel structures (example: brush coatings)10 to 50 Pa
viscoelastic gels (typical dispersions, lotions, creams, ointments, pastes of food, cosmetics, pharmaceuticals, medicals)50 to 5000 Pa (often100 to 500 Pa)
puddings (containing 5/7.5/10/15 % starch)0.1/0.5/1/5 kPa
adhesives before hardening– soft paste structure– strong structure, e. g. filled sealants0.1 to 10 kPa50 to 500 kPa
gummy bears, jelly babies10 to 500 kPa
spread cheese/soft cheese/semi-hard/hard/extra hard cheese1 kPas/10 kPas/0.1 MPa/0.5 MPa/1 MPa
butter (example): at T = +10/+23 °C2 MPa/50 kPa
soft natural gumsunfilled gumsfilled gumseraser gum (India rubber)technical elastomershard rubbers (e. g. car tires)0.03 to 0.3 MPa0.3 to 5 MPa3 to 20 MPa1 MPa0.3 to 30 MPa10 to 100 MPa0.490.40 to 0.450.35 to 0.400.40 to 0.450.35 to 0.400.1 to 1 MPa1 to 10 MPa10 to 50 MPa1 to 100 MPa30 to 300 MPa
PU coating, highly viscous/rigidone-pack PU adhesivetwo-pack PU reactive adhesive30 kPa/1.0 GPa1 to 10 MPa200 to 600 MPa100 kPa/2.5 GPa
bitumen (example):at T = 0/-10/-30/-50 °C10/50/200/500 MPa
thermoplastic polymers,unfilled, uncrosslinked (usually)0.1 to 2 GPa0.30 to 0.351 to 4 GPa
PE-LDPE-HD70 to 200 MPa300 to 800 MPa0.480.38200 to 600 MPa0.7 to 2 GPa
PPPP, filled0.2 to 0.5 GPa1 to 3 GPa0.350.250.5 to 1.3 GPa1.8 to 6.5 GPa
PVC-P (plasticized, flexible,Tg > +20 °C)PVC-U (unplasticized, rigid)PVC, filled0.5 to 5 MPa0.3 to 1 GPa1 to 3 GPa0.400.350.251.5 to 15 MPa1 to 3 GPa3 to 8 GPa
PEEK-CF(with 40/65 % carbon fibers)up to80/155 GPa
pure resinsfilled and fiber-reinforced resins(dependent on the fiber orientation)1 to 2 GPa2 to 12 (24) GPa0.400.25 to 0.353 to 5 GPa5 to 30 (60) GPa
wood (axial)wood (radial)4 to 18 GPa0.3 to 0.6 GPa
MaterialG modulusμE modulus
ice (at T = -4 °C)3.7 GPa0.339.9 GPa
bone18 to 21 GPa
ceramics, porcelain15 to 35 GPa, 25 GPa0.2040 to 80 GPa
marble stone28 GPa0.3070 GPa
(window) glass30 GPa0.1570 GPa
aluminum (Al 99.9 %)28 GPa0.3472 GPa
gold (Au)28 GPa0.4281 GPa
brass (Cu-Zn)36 GPa0.37100 GPa
cast iron40 GPa0.25100 GPa
bronze (Cu-Sn)43 GPa0.35116 GPa
steel80 GPa0.28210 GPa
diamonds1200 GPa

      BrilleFor “Mr. and Ms. Cleverly“

      Information on parameters obtained from tensile tests

      Conversion of G- and E-values

      Equation 4.5

      E = 2 · G (1 + μ)

      with the tensile modulus E [Pa], often called modulus of elasticity or Young’s modulus , and Poisson’s ratio μ with the unit [1], (my, pronounced: mu or mew). For a brief information on Thomas Young (1773 to 1829 [4.6]) and Siméon D. Poisson (1781 to 1840, [4.7]), see Chapter 14.2. Poisson’s ratio µ is the value of the ratio of the lateral (transversal) deformation to the corresponding axial deformation, resulting from uniformly distributed axial stress below the proportional limit of the material (according to ASTM D4092; by the way, in this standard instead of the sign μ the sign ν is used). The following holds (e. g. according to DIN 13316):

      Equation 4.6

      0 ≤ μ ≤ 0.5

      The higher the value of Poisson’s ratio, the more ductile is a material; or: The lower the μ-value, the more brittle is its behavior when breaking. Cork, showing μ = 0, is a material with one of the two extreme values. Therefore here

      Equation 4.7

      E = 2 · G

      On the other hand, for viscoelastic liquids occurs the other extreme value of µ = 0.50. In this case, there is no volume change when stressing or straining these kinds of materials. Close to that value are soft and very flexible rubbers showing μ = 0.49. The same value occurs when testing polymers exhibiting behavior of viscoelastic liquids at temperatures above the glass-transition temperature (T > Tg), because then, they are in a soft-elastic (or rubber-elastic) state. This applies also to other incompressible and isotropic materials. Hence, for these kinds of materials counts:

      Equation 4.8

      E = 3 · G

      Note: Conversion of G- and E-modulus values

      In general, calculation of G-values from E-values, and vice versa, is not recommended since there is evidence that suggests the Poisson’s ratio varies from material to material in the same material class and may vary from temperature to temperature for the same material (according to ASTM D1043). Therefore, these conversions must be regarded as rough estimates only.

      Stress/strain diagrams (SSD) of tensile tests

      Performing tensile tests, E-modulus values are determined in the linear-elastic range, i. e. in a range of very low strain values. In this range of a σ/ε diagram, the curve function shows a constant slope. The following applies here:

      Equation 4.9

      E = σ/ε

      with the tensile stress σ [Pa], (pronounced: sigma), and the tensile strain or elongation ε in [%], (pronounced: epsilon). Further information on tensile tests can be found in Chapters 10.8.4.1 and 11.2.14; ISO 6721, ISO 6892; DIN 50125 and [4.8] [4.9] [4.10] [4.11] [4.12].

      BrilleEnd of the Cleverly section

      deformation behavior

      4.2.1.1.1Experiment 4.1: Playing with a spiral spring

      When a constant tensile or compression load is applied to the spring, it immediately deforms to a constantly remaining degree of deflection. After removing the load, the spring immediately recoils to the initial position.

      4.2.1.1.2Experiment 4.2: Playing with a steel ball