From his analysis of the solar spectrum, Newton concluded, “that to the same degree of refrangibility ever belonged the same colour, and to the same colour ever belonged the same degree of refrangibility;” and hence he inferred, that red, orange, yellow, green, blue, indigo, and violet were primary and simple colours. He admitted, indeed, that “the same colours in specie with these primary ones may be also produced by composition. For a mixture of yellow and blue makes green, and of red and yellow makes orange;” but such compound colours were easily distinguished from the simple colours of the spectrum by the circumstance, that they are always capable of being resolved by the action of the prism into the two colours which compose them.
This view of the composition of the spectrum might have long remained unchallenged, had we not been able to apply to it a new mode of analysis. Though we cannot separate the green rays of the spectrum into yellow and blue by the refraction of prisms, yet if we possessed any substance which had a specific attraction for blue rays, and which stopped them in their course, and allowed the yellow rays to pass, we should thus analyze the green as effectually as if they were separated by refraction. The substance which possesses this property is a purplish blue glass, similar to that of which finger-glasses are made. When we view through a piece of this glass, about the twentieth of an inch thick, a brilliant prismatic spectrum, we find that it has exercised a most extraordinary absorptive action on the different colours which compose it. The red part of the spectrum is divided into two red spaces, separated by an interval entirely devoid of light. Next to the inner red space comes a space of bright yellow, separated from the red by a visible interval. After the yellow comes the green, with an obscure space between them, then follows the blue and the violet, the last of which has suffered little or no diminution. Now it is very obvious, that in this experiment, the blue glass has actually absorbed the red rays, which, when mixed with the yellow on one side, constituted orange, and the blue rays, which, when mixed with the yellow on the other side, constituted green, so that the insulation of the yellow rays thus effected, and the disappearance of the orange, and of the greater part of the green light, proves beyond a doubt that the orange and green colours in the spectrum are compound colours, the former consisting of red and yellow rays, and the latter of yellow and blue rays of the very same refrangibility. If we compare the two red spaces of the spectrum seen through the blue glass with the red space seen without the blue glass, it will be obvious that the red has experienced such an alteration in its tint by the action of the blue glass, as would be effected by the absorption of a small portion of yellow rays; and hence we conclude, that the red of the spectrum contains a slight tinge of yellow, and that the yellow space extends over more than one-half of the spectrum, including the red, orange, yellow, green, and blue spaces.
I have found also that red light exists in the yellow space, and it is certain that in the violet space red light exists in a state of combination with the blue rays. From these and other facts which it would be out of place here to explain, I conclude that the prismatic spectrum consists of three different spectra, viz. red, yellow, and blue, all having the same length, and all overlapping each other. Hence red, yellow, and blue rays of the very same refrangibility coexist at every point of the spectrum; but the colour at any one point will be that of the predominant ray, and will depend upon the relative distance of the point from the maximum ordinate of the curve which represents the intensity of the light of each of the three spectra.
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