12 PART VI: ASYMMETRIC CARBON–CARBON BOND FORMING REACTIONS CHAPTER 16 ASYMMETRIC NUCLEOPHILIC ADDITION TO KETONES AND KETIMINES AND CONJUGATE ADDITION REACTIONS 16.1. INTRODUCTION 16.2. ASYMMETRIC NUCLEOPHILIC ADDITION TO KETONES 16.3. ASYMMETRIC NUCLEOPHILIC ADDITION TO KETIMINES 16.4. CATALYTIC ASYMMETRIC CONJUGATE ADDITION 16.5. CONCLUSIONS ACKNOWLEDGMENTS REFERENCES 17 ASYMMETRIC ALLYLIC ALKYLATION, ALLYLATION, AND RELATED REACTIONS 17.1. INTRODUCTION AND SCOPE 17.2. PALLADIUM‐CATALYZED ENANTIOSELECTIVE ALLYLIC ALKYLATIONS 17.3. NICKEL‐ AND PLATINUM‐CATALYZED ALLYLIC ALKYLATION 17.4. MOLYBDENUM‐ AND TUNGSTEN‐CATALYZED ENANTIOSELECTIVE ALLYLIC ALKYLATION 17.5. IRON‐ AND RUTHENIUM‐CATALYZED ALLYLIC ALKYLATION 17.6. RHODIUM‐CATALYZED ENANTIOSELECTIVE ALLYLIC ALKYLATION 17.7. IRIDIUM‐CATALYZED ENANTIOSELECTIVE ALLYLIC ALKYLATION 17.8. COPPER‐CATALYZED ENANTIOSELECTIVE ALLYLIC ALKYLATION 17.9. COBALT‐CATALYZED ENANTIOSELECTIVE ALLYLIC ALKYLATION 17.10. CONCLUDING REMARKS REFERENCES 18 ASYMMETRIC CARBOMETALLATIONS INCLUDING CARBOCYCLIZATIONS 18.1. INTRODUCTION 18.2. CARBOMETALLATIONS WITH MAIN GROUP METALS 18.3. CARBOMETALLATIONS WITH TRANSITION METALS 18.4. CONCLUSION REFERENCES
13 PART VII: ASYMMETRIC SYNTHESIS OF NON‐CENTRO‐CHIRAL COMPOUNDS 19 ASYMMETRIC SYNTHESIS OF AXIALLY CHIRAL COMPOUNDS 19.1. INTRODUCTION 19.2. METAL CATALYSIS 19.3. ORGANOCATALYSIS 19.4. ENZYMATIC CATALYSIS 19.5. CONCLUSION REFERENCES 20 ASYMMETRIC SYNTHESIS OF PLANAR CHIRAL AND HELICALLY CHIRAL COMPOUNDS 20.1. INTRODUCTION 20.2. ENANTIOSELECTIVE SYNTHESIS OF PLANAR CHIRAL COMPOUNDS 20.3. ENANTIOSELECTIVE SYNTHESIS OF HELICALLY CHIRAL COMPOUNDS 20.4. SUMMARY REFERENCES
14 PART VIII: ASYMMETRIC POLYMERIZATION 21 ASYMMETRIC POLYMERIZATION 21.1 INTRODUCTION 21.2 ENANTIOSELECTIVE POLYMERIZATION 21.3 HELIX‐SENSE‐SELECTIVE POLYMERIZATIONS 21.4 SUMMARY AND OUTLOOK REFERENCES
15 PART IX: ASYMMETRIC CATALYSIS IN CONTINUOUS‐FLOW SYSTEM 22 CONTINUOUS‐FLOW CHEMISTRY IN CATALYTIC ASYMMETRIC SYNTHESIS 22.1. INTRODUCTION 22.2. OVERVIEW OF CATALYTIC PROCESSES IN FLOW ORGANIC SYNTHESIS 22.3. ENANTIOSELECTIVE C–C BOND‐FORMING REACTIONS THROUGH 1,4‐ADDITION REACTIONS 22.4. ENANTIOSELECTIVE C–C BOND‐FORMING REACTIONS THROUGH 1,2‐ADDITION REACTIONS 22.5. ENANTIOSELECTIVE C–C BOND FORMATION THROUGH CYCLOADDITION REACTIONS 22.6. ENANTIOSELECTIVE C–C BOND‐FORMING REACTIONS THROUGH HYDROFORMYLATION 22.7. ENANTIOSELECTIVE C–X BOND‐FORMING REACTIONS THROUGH OXIDATIVE PROCESSES 22.8. ENANTIOSELECTIVE REDUCTION OF DOUBLE BONDS THROUGH CONTINUOUS‐FLOW SYSTEMS 22.9. CONCLUSION AND OUTLOOK REFERENCES
16 INDEX
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