25 18 AIE‐active Polymer 18.1 Introduction 18.2 Photophysical Properties 18.3 Applications 18.4 Conclusion and Perspective Acknowledgments References
26 19 Liquid‐crystalline AIEgens 19.1 Introduction 19.2 Materials: Molecular Design 19.3 Applications of LC AIEgens 19.4 Conclusion References
27 20 Push–Pull AIEgens 20.1 Introduction 20.2 Basic Concept of Molecular Design 20.3 Push–Pull AIEgens from Rotor Structure 20.4 Push–Pull AIEgens from ACQ Chromophores 20.5 Concluding Remarks References
28 Index
List of Tables
1 Chapter 2Table 2.1 Calculated HOMO–LUMO energy gap (∆E g), electric transition dipole...Table 2.2 Calculated k r, k ic, and Φ F in both solution and aggregate ph...Table 2.3 Calculation structural parameters of COTh [43] in both gas phase ...Table 2.4 The calculated spectral properties and reorganization energies co...Table 2.5 Calculated k r, k ic, and Φ F in both solution and aggregate ph...Table 2.6 Calculated room‐temperature k ic (s−1) for nondeuterated (H‐...
2 Chapter 4Table 4.1 Data of single crystals.Table 4.2 Optical properties and single‐crystal information of the compound...
3 Chapter 7Table 7.1 Absorption maxima (λ max) of molecules with and without clay ...Table 7.2 The fluorescence quantum yields of various molecules in a bulk so...
4 Chapter 8Table 8.1 Photophysical parameters of DMF‐BP‐PXZ, DPF‐BP‐PXZ, and SBF‐BP‐PX...Table 8.2 The key electroluminescence data of the AIDF materials.
5 Chapter 10Table 10.1 Comparison between current HAITE and AIE.
6 Chapter 12Table 12.1 Comparative photophysical properties of derivatives 8‐10....
7 Chapter 14Table 14.1 Emission quantum efficiencies (Φ fl) of HC and HP molecular ...
8 Chapter 20Table 20.1 Photophysical properties of BT‐based AIEgens.Table 20.2 Photophysical properties of compounds 77–82.Table 20.3 Photophysical properties of DPP‐based AIEgens in solution and ag...Table 20.4 Photophysical properties of PBI‐based AIEgens in solution and ag...
List of Illustrations
1 Chapter 1Figure 1.1 (a) Fluorescence quantum yield of HPS in the acetone/water mixtur...Figure 1.2 (a) UV–vis absorption and (b) photoluminescence (PL) spectra of c...Figure 1.3 Schematic illustration of RIM mechanism. (a) Restriction of intra...Figure 1.4 (a) Chemical structures of TPE derivatives with increasing rigidi...Figure 1.5 (a) Chemical structures and the overlap of the S1,min conformatio...Figure 1.6 (a) Chemical structures, the overlaps of the S1,min conformation ...Figure 1.7 (a) Chemical structures and fluorescence quantum yield in the dil...Figure 1.8 (a) Illustration of the coupling between the bright state and the...Figure 1.9 Molecular structure, calculated energy levels, fluorescence, and ...Figure 1.10 (a) Schematic illustration of the cluster formation, energy vari...Figure 1.11 Schematic illustration of the excited‐state (a) intramolecular t...
2 Chapter 2Figure 2.1 (a) Setup of the PCM model for an isolated molecule in solution; ...Figure 2.2 (a) PES scheme of AIEgens in solution and solid states. (b–g) Ove...Figure 2.3 Overview of molecular structures discussed in Sections 2.3 and 2....Figure 2.4 Calculated reorganization energies versus normal mode of (a) HPS,...Figure 2.5 (a) The schematic representation of the adiabatic potential energ...Figure 2.6 (a) Calculated λj versus ωj in both solution and solid ...Figure 2.7 (a) Representation of the isotope effect on k ic. (b) IE results f...Figure 2.8 (a) The average packing density of amorphous HPS aggregates. (b) ...Figure 2.9 (a) Reorganization energies λ g(e) and excitonic couplings J ...Figure 2.10 (a) The QM/MM model of TTVP in lipid membrane. (b, c) Calculated...