[Of late years the interesting art of painting on glass has attracted considerable attention; lovers of the fine arts, antiquaries, and chemists, have contributed to its perfection, and have sought to ascertain by what methods their predecessors were able to give those beautiful and brilliant tints to their productions, many of which have been so wantonly destroyed by the barbarity of the last century333. One of the most ingenious essays that has been written on the subject, is that published by an anonymous correspondent in the Philosophical Magazine for December 1836, which we subjoin in elucidation of our present knowledge on the subject.
On the Art of Glass-Painting. By a Correspondent.
It is a singular fact, that the art of glass-painting, practised with such success during the former ages from one end of Europe to the other, should gradually have fallen into such disuse, that in the beginning of the last century it came to be generally considered as a lost art. In the course of the eighteenth century, however, the art again began to attract attention, and many attempts were made to revive it. It was soon found by modern artists, that by employing the processes always in use among enamel-painters, the works of the old painters on glass might in most respects be successfully imitated; but they were totally unable to produce any imitation whatever of that glowing red which sheds such incomparable brilliancy over the ancient windows that still adorn so many of our churches334. For this splendid colour they possessed no substitute, until a property, peculiar to silver alone among all the metals, was discovered, which will presently be described. The art of enamelling on glass differs little from the well-known art of enamelling on other substances. The colouring materials (which are exclusively metallic) are prepared by being ground up with a flux, that is, a very fusible glass, composed of silex, flint-glass, lead, and borax: the colour with its flux is then mixed with volatile oil, and laid on with the brush. The pane of glass thus enamelled is then exposed to a dull red heat, just sufficient to soften and unite together the particles of the flux, by which means the colour is perfectly fixed on the glass. Treated in this way, gold yields a purple, gold and silver mixed a rose-colour, iron a brick-red, cobalt a blue335; mixtures of iron, copper and manganese, brown and black. Copper, which yields the green in common enamel-painting336, is not found to produce a fine colour when applied in the same way to glass, and viewed by transmitted light; for a green therefore recourse is often had to glass coloured blue on one side and yellow on the other. To obtain a yellow, silver is employed, which, either in the metallic or in any other form, possesses the singular property of imparting a transparent stain, when exposed to a low red heat in contact with glass. This stain is either yellow, orange, or red, according to circumstances. For this purpose no flux is used: the prepared silver is merely ground up with ochre or clay, and applied in a thick layer upon the glass. When removed from the furnace the silver is found not at all adhering to the glass; it is easily scraped off, leaving a transparent stain, which penetrates to a certain depth. If a large proportion of ochre has been employed, the stain is yellow; if a small proportion, it is orange-coloured; and by repeated exposure to the fire, without any additional colouring matter, the orange may be converted into red. This conversion of orange into red is, I believe, a matter of much nicety, in which experience only can ensure success. Till within a few years this was the only bright red in use among modern glass-painters; and though the best specimens certainly produce a fine effect, yet it will seldom bear comparison with the red employed in such profusion by the old artists.
Besides the enamels and stains above-described, artists, whenever the subject will allow of it, make use of panes coloured throughout their substance in the glass-house melting-pot, because the perfect transparency of such glass gives a brilliancy of effect, which enamel-colouring, always more or less opake, cannot equal. It was to a glass of this kind that the old glass-painters owed their splendid red. This in fact is the only point in which the modern and ancient processes differ, and this is the only part of the art which was ever really lost. Instead of blowing plates of solid red, the old glass-makers used to flash a thin layer of red over a substratum of plain glass. Their process must have been to melt side by side in the glass-house a pot of plain and a pot of red glass: then the workman, by dipping his rod first into the plain and then into the red glass pot, obtained a lump of plain glass covered with a coating of red, which, by dexterous management in blowing and whirling, he extended into a plate, exhibiting on its surface a very thin stratum of the desired colour337. In this state the glass came into the hands of the glass-painter, and answered most of his purposes, except when the subject required the representation of white or other colours on a red ground: in this case it became necessary to employ a machine like the lapidary’s wheel, partially to grind away the coloured surface till the white substratum appeared.
The material employed by the old glass-makers to tinge their glass red was the protoxide of copper, but on the discontinuance of the art of glass-painting the dependent manufacture of red glass of course ceased, and all knowledge of the art became so entirely extinct, that the notion generally prevailed that the colour in question was derived from gold338. It is not a little remarkable that the knowledge of the copper-red should have been so entirely lost, though printed receipts have always existed detailing the whole process. Baptista Porta (born about 1540) gives a receipt in his Magia Naturalis, noticing at the same time the difficulty of success. Several receipts are found in the compilations of Neri, Merret and Kunckel, from whence they have been copied into our Encyclopædias339. None of these receipts however state to what purposes the red glass was applied, nor do they make any mention of the flashing. The difficulty of the art consists in the proneness of the copper to pass from the state of protoxide into that of peroxide, in which latter state it tinges glass green. In order to preserve it in the state of protoxide, these receipts prescribe various deoxygenating substances to be stirred into the melted glass, such as smiths’ clinkers, tartar, soot, rotten wood, and cinnabar.
One curious circumstance deserves to be noticed, which is, that glass containing copper when removed from the melting-pot sometimes only exhibits a faint greenish tinge, yet in this state nothing more than simple exposure to a gentle heat is requisite to throw out a brilliant red. This change of colour is very remarkable, as it is obvious that no change of oxygenation can possibly take place during the recuisson.
The art of tinging glass by protoxide of copper and flashing it on crown-glass, has of late years been revived by the Tyne Company in England, at Choisy in France340, and in Suabia in Germany, and in 1827 the Academy of Arts at Berlin gave a premium for an imperfect receipt. To what extent modern glass-painters make use of these new glasses I am ignorant; the specimens that I have seen were so strongly coloured as to be in parts almost opake, but this is a defect which might no doubt be easily remedied341.
I shall now conclude these observations by a few notices respecting glass tinged by fusion with gold, which, though never brought into general use among glass-painters, has I know been employed in one or two instances, flashed both on crown- and on flint-glass. Not long after the time when the art of making the copper-red glass was lost, Kunkel appears to have discovered that gold melted with flint-glass was capable of imparting to it a beautiful ruby colour. As he derived much profit from the invention, he kept his method secret, and his successors have done the same to the present day. The art, however, has been practised ever since for the purpose of imitating precious stones, &c., and the glass used to be sold at Birmingham for a high price under the name of Jew’s glass. The rose-coloured scent-bottles, &c., now commonly made,