Anderson says, in his History of Commerce35, that in the second volume of Hakluyt there is a letter which shows the use of quicksilver to have been a new invention in the year 1572. This letter I found, not in the second, but in the third and last volume of the Voyages collected by Hakluyt36. It was written in the above year by a merchant named Henry Hawks, and contains only the following information: “A good owner of mines must have much quicksilver; and as for this charge of quicksilver, it is a new invention, which they find more profitable than to fine their ore with lead.”
Gobet, in a work entitled The Ancient Mineralogists of France, accuses Alphonso Barba of asserting that he found out amalgamation in the year 1609. To examine this charge, it will be necessary to give some account of the metallurgic works of that Spaniard, which, perhaps, may not prove unacceptable to those who are fond of metallurgy and mineralogy. Alvaro Alphonso Barba was born at Lepe, a small town in Andalusia, and officiated many years as clergyman of the church of St. Bernard, at Potosi. The first edition of this work was printed in quarto, at Madrid, in 1640, in the Spanish language, and illustrated with cuts. This book the Spaniards for a long time concealed, because they considered it as containing all their metallurgic secrets; though at that time there were much better works of the kind in Germany, and though amalgamation had been long known and practised. Edward earl of Sandwich, being ambassador to Spain, found however an opportunity of procuring a copy of it, as a great rarity; and he began a translation of it into English, but translated only the first two books. This translation was published at London in octavo, in 1674, after the earl’s death, and entitled The First Book of the Art of Metals, in which is declared the manner of their generation, and the concomitants of them. Written in Spanish by Albaro Alonso Barba, translated by the earl of Sandwich. From this English edition several German translations have been made, of which I am acquainted with the following: two at Hamburg, one printed in 1676, and the other in 1696; and two at Frankfort, one in 1726, and another in 1739. In the year 1749 a new edition appeared at Vienna. This edition, which is very different from any of the former, was translated from the French by one Godar, who was not a German, and who on that account apologises in the preface for the badness of his style. All these editions however are imperfect; for the original contains five books, as we learn from Leibnitz, who caused them to be transcribed. In the year 1751 a new translation came out at Paris, entitled Metallurgy, or the art of extracting and purifying metals, translated from the Spanish of Alphonso Barba, by M. Gosfort, with the most curious dissertations on mines and metallic operations; of this translation the celebrated abbé Lenglet de Fresnoy is said to have been the editor37.
To judge by two of the German editions, Gobet has done Barba an injustice. In that of 1676, I find Barba expressly says he does not believe the ancients were acquainted with the art of extracting silver from pounded ore by the means of quicksilver. This certainly does not indicate that he laid claim to the invention; besides, he everywhere speaks of amalgamation as an art long used in America, but complains of the negligence with which it was practised. In a passage however in the Vienna edition, and which has probably been added by Gobet, we are told that in the year 1609, Barba attempted to fix quicksilver, and with that view bethought himself of mixing it with finely pounded silver ore; that he at first imagined, with surprise, that he had obtained a mass of silver, but that he soon perceived that the mercury was not changed into silver, but had only attracted the particles of that metal. “I was,” adds Barba, “highly pleased with my new discovery of managing ore, of extracting its contents, and of refining it; and this method I continued to practise.” I imagine that Barba was still in Europe in 1609, and made that experiment before he was acquainted with the smelting-works in America. I am however of opinion, that one will see by the original that Barba did not wish to claim the invention of amalgamation as practised in the mines of America.
FOOTNOTES
28 [Among the improvements of recent date there are perhaps none of greater importance than those of electro-gilding and gilding by immersion, which have almost entirely superseded the process of gilding by an amalgam of mercury and gold, so fatal to the workmen exposed to the deleterious effects of the mercurial vapours. It is not our intention to enter at present into a history of the invention of these processes; they will more properly be reserved for a future volume, in which the discoveries of the present century will be treated of. The following short outline may however not prove uninteresting to the reader:—It had long been known to experimentalists on the chemical action of voltaic electricity, that solutions of several metallic salts were decomposed by its agency, and the metal produced in its free state. The precipitation of copper by the voltaic current was noticed by Mr. Nicholsona in a paper entitled ‘Account of the new Electrical Apparatus of Sig. Alex. Volta, and experiments performed with the same;’ but the earliest recorded process in electro-gilding is probably that contained in a letter from Brugnatelli to Van Monsb, in which he states that he had deposited a film of gold on ten silver medals by bringing them into communication by means of a steel wire with the negative pole of a voltaic pile, and keeping them one after the other immersed in ammoniuret of gold newly made and well-saturated. This announcement of a process identical with those now extensively used, attracted no attention at the time it was made, and no further experiments on the application of electricity to the deposition of metals for the purposes of the arts were published until the year 1830, when Mr. E. Davy read a paper before the Royal Society, in which he distinctly states that he had gilded, silvered, coppered and tinned various metals by the voltaic batteryc. The experiments of Brugnatelli and Davy were however completely lost sight of, and the art may be said to date its origin from the period when the late Professor Daniell described his constant battery. Since that time the art has continued to advance most rapidly, either in the perfecting of the apparatus or in the pointing out of more suitable salts of gold and silver, from which the metals might be precipitated. Among those who have contributed to its advancement we may particularly instance the names of our countrymen, Woolrich, Spencer, Jordan, Mason, Murray, Smee, Elkington, Fox Talbot, and Tuck. Nearly all the gilt articles manufactured at Birmingham are now gilded by the process patented by Mr. Elkington, in which, after the articles have been cleansed by a weak acid, they are placed in a hot solution of nitro-muriate of gold, to which a considerable excess of bicarbonate of potash has been added; in the course of a few seconds they thus receive a beautiful and permanent coating of gold.]
a Nicholson’s Journal, July 1800, p. 179.
b Philosophical Magazine, 1805.
c Phil. Trans. 1831, p. 147.