The volume resistance Rv measured through a material of volume resistivity ρv using electrodes of area A is given by
where t = A = 1, or t/A = 1, which reduces to ρv = Rv.
The unit of volume resistivity is ohm meter (Ωm). The volume resistivity of a material is often simply referred to as its resistivity.
In practice, standards exist for measuring volume resistivity using concentric ring electrodes (IEC 62631‐3‐1 (International Electrotechnical Commission 2016c), IEC 61340‐2‐3 (International Electrotechnical Commission 2016b), ANSI/ESD STM 11.12 (EOS/ESD Association Inc. 2015b))
Figure 1.3 Definition of volume resistivity.
Volume resistance, Rv, is a resistance measured between opposing faces of a material. The electrodes may be of any convenient form. Often this measurement is made using electrodes designed for volume resistivity measurement so that conversion from volume resistance to volume resistivity is a simple calculation. In ESD work, conversion to volume resistivity is often not needed. The volume resistance obtained with defined standard electrodes is used directly, saving the effort of calculation. Examples of surface and volume resistance measurement methods are given in Chapter 11.
The conductivity, σ, of the material is simply the inverse of its resistivity.
The units of conductivity are siemens per meter (Sm−1).
The resistivity of materials can vary by many orders of magnitude from 10−8 Ωm (e.g. copper) to more than 1015 Ωm (e.g. mica, quartz, polytetrafluoroethylene, polyethylene).
1.7.3 Insulators, Conductors, Conductive, Dissipative, and Antistatic Materials
There is no fundamental definition of insulators and conductors in electrostatics. In reality, there is a continuum of material resistivity from highly conducting (low resistance) to highly insulating (very high resistance). Different industry areas may have differing views on the resistance level at which a material is considered to have insulating properties.
For our purposes, a conductor is a material that allows charge to move around on the surface or in the bulk of the material and can thereby be used to transport charge from one place to another. An insulator (nonconductor) is a material that does not allow the charge to move in this way.
One problem in practice is that a material that is considered “insulating” in one application may be considered significantly conducting in electrostatics. So, for some years I have offered the following pragmatic definitions for use in practical electrostatics and ESD control:
A conductor is a material that allows charge to move away quickly enough to avoid significant electrostatic charge build up.
An insulator is any material that is not a conductor, in other words, a material that does not allow charge to move quickly enough to avoid charge build up.
Conductors are easily maintained at a low voltage by connecting them to earth (ground). However, an insulator in electrostatic terms cannot be maintained at a low voltage by installing a ground connection. The charge on the material simply does not move to the ground connection quickly enough to be conducted away in the desired timescale.
Materials or equipment are often defined as conductors or insulators based on either their measured resistance or a charge decay time. This is discussed further in Chapter 2.
Table 1.2 shows how the terms insulating, dissipative, conductive, and antistatic are widely used in ESD control. Take care when using these terms, because they may be defined differently in different contexts and may mean different things to different people. When defined in the standards, the precise definition can change as the standards evolve into new editions.
The situation becomes worse if usage of these terms in other industries and for specific products is considered (Table 1.3). In general, these words should be considered unreliable in meaning unless specified by standards as part of an ESD control system.
Table 1.2 Example of how meanings of conductive, static dissipative, insulative, and antistatic can vary with context in ESD control in electronic manufacturing.
| Term | Application | General use | Meaning under 61340‐5‐1:2016a | Meaning under S20.20‐2014 |
| Conductive | General | Resistance <106 Ω | Not defined | Not defined |
| ESD control footwear | Not defined | Not defined | ||
| ESD control flooring | <106 Ω | Not defined | Not defined | |
| ESD protective packaging | Surface resistance <104 Ω | Surface and volume resistance <104 Ω | ||
| Static dissipative | General | Resistance between 106 and 1011 Ω | Not defined | Not defined |
| ESD control footwear | Not defined | Not defined | ||
| ESD control flooring | ≥106 Ω | Not defined | Not defined | |
| ESD protective packaging | Surface resistance ≥104 and ≤1011 Ω | Surface and volume resistance ≥104 and <1011 Ω | ||
| Insulative | General | Resistance over 1011 Ω | Not defined | Not defined |
| ESD control footwear | Not defined, but by implication >108 Ω |
Not defined, but by implication resistance >109 Ω
|