Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata. Читать онлайн. Newlib. NEWLIB.NET

Автор: F. Xavier Malcata
Издательство: John Wiley & Sons Limited
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Жанр произведения: Химия
Год издания: 0
isbn: 9781119490333
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      – as illustrated in Fig. 2.10c. Since this function repeats itself every 2π rad, i.e.

      (2.310)equation

      (2.311)equation

      with the aid of Eq. (2.296), so the secant is an even function and thus symmetrical with regard to the vertical axis. The secant is not a monotonic function; it decreases and then increases within](2k − 1)π/2,(2k + 1)π/2[ for even integer k, with vertical asymptotes at the extremes, or vice versa with odd integer k.

      Finally, the cosecant of angle θ is given by the ratio of the length of the hypotenuse, [OB], to the length of the opposite leg, [AB], in triangle [OAB] – or, equivalently, as the secant of the complementary angle of θ, i.e. the ratio of the length of the hypotenuse, [OE], to the length of the adjacent leg, [OB], in triangle [OBE], i.e.

      – as plotted in Fig. 2.10d. A period of 2π rad is again found, viz.

      (2.315)equation

      (2.316)equation

      with the aid of Eq. (2.295), should the argument be replaced by its negative – so the cosecant is symmetrical with regard to the origin of the axes, as per its odd behavior. Note that the cosecant increases and then decreases within](2k − 1)π,2[ for integer k, bounded by vertical asymptotes described by x = (2k − 1)π and x = 2, respectively, and the other way round within]2kπ,(2k + 1)π[.

      2.3.2 Angle Transformation Formulae

      Referring again to Fig. 2.10a, one may label as u1 the unit vector centered at the origin, defining an angle θ1 with the horizontal axis – with coordinates (cos θ1, sin θ1) as per Eqs. (2.288) and (2.290); and likewise as u2 the unit vector centered at O but defining an angle θ2 – with coordinates (cos θ2, sin θ2), with θ2 > θ1 for simplicity. Under these circumstances, the scalar product of u1 and u2 (to be discussed later) reads

      where θ2θ1 > 0 represents the amplitude of the angle defined by vectors u1 and u2, i.e. ∠ u1, u2. As will be duly proven below, u1 · u2 may instead be calculated via

      this is equivalent to