In the works of the old mineralogists, fluor-spar is either not mentioned, or is classed among their natural glasses and precious stones; and in those of the first systematic writers it is so mingled with quartz and calcareous and gypseous spars, that it is impossible to discover it. The old German miners, however, distinguished it so early as the sixteenth century, and called it fluss; because they used it to accelerate the fusion of ores that were difficult to be reduced to that state. Agricola, who first remarked this, changed the German name into fluor, an appellation, which, like many others, formed by him from German words, such for example as quarzum from quarz, spatum from spat, wismuthum, zincum, cobaltum, &c., became afterwards common. If a passage of the ancients can be quoted that seems to allude to fluor-spar, it is that of Theophrastus, where he says that there are certain stones which, when added to silver, copper, and iron ores, become fluid225. The first systematic writer who mentioned this kind of stone as a particular genus, was Cronstedt.
Besides being known by its metallurgic use, fluor-spar is known also by having the colours of some precious stones, so that it may be sold, or at least shown as such to those who are not expert judges; because the first time when heated in the dark it shines with a bluish-green lustre. It is possible that fluor-spar may have been among the number of that great variety of stones which the ancients, with much astonishment, tell us shone in the dark; though it is certain that the principal part of them were only light-magnets, as they are called, or such as retain for a certain period the light they have absorbed in the day-time. The observation, however, that fluor-spar emits light after it is heated, seems to have been first made when artificial phosphorus excited the inquiry of naturalists and chemists; and when they began to search in their own country for stones which, in the property of emitting light, might have a resemblance to the Bologna spar, made known about the year 1630. It is well known that the latter is prepared for that purpose by calcination. Stones of the like kind were sought for; and among these fluor-spar, which is not scarce in Germany.
In my opinion, the observation was made in the year 1676; for in that year Elsholz informed the members of the Society for investigating Nature, that he was acquainted with a phosphorus which had its light neither from the sun nor from fire, but which, when heated on a metal plate over glowing coals, shone with a bluish-white lustre; so that by strewing the powder of it over paper, one might form luminous writing. I doubt much whether this experiment was ever tried; at least I find no further account of it in the papers of the Society, nor in the re-publication of the above author’s first dissertation, which appeared in 1681226.
As far as I know, Kirchmaier, professor at Wittenberg, was the first who disclosed the secret, in the year 1679227. Both call this phosphorus the smaragdine; because the ancients speak much of luminous emeralds, and because green fluor-spar is often exhibited as an emerald. Kirchmaier calls this mineral also hesperus and vesperugo; and these names have been often given since to fluor-spar, as in the receipt before-mentioned for making a liquid to etch on glass. Kirchmaier’s information, however, must have been very little known; for the Jesuit Casatus, who, in 1684, wrote his Treatise on Fire, was not acquainted with it, as he has inserted only the words of Elsholz. This observation must have been new to Leibnitz himself, and to the Academy of Sciences at Berlin, in 1710; for the former then mentioned it to the Society as a philosophical novelty228.
I shall remark, in the last place, that the manufacturing of vessels and ornaments of every kind from solid fluor-spar was begun in Derbyshire in the year 1765229. The articles formed of it are in England called spar ornaments, and sometimes blue John. Many beautiful colours must, as is said, be brought forward by means of fire. But the heat must be applied with great caution; for fluor-spar, as is well known, by a strong and particularly a sudden heating, cracks, and loses its transparency. Since writing the above, I find that M. Raspe230 denies this bringing forward of colours by fire.
SOAP
That the first express mention of soap occurs in Pliny and Galen, and that the former declares it to be an invention of the Gauls, though he prefers the German to the Gallic soap231, has already been remarked by many. Pliny says that soap232 was made of tallow and ashes; that the best was made of goats’ tallow and the ashes of the beech-tree, and that there were two kinds of it, hard and soft. The author of a work on simple medicines, which is ascribed to Galen, but which however does not seem to have been written by that author, and of which only a Latin translation has been printed, speaks of soap being made by a mixture of oxen, goats’, or sheep’s tallow, and a lye of ashes strengthened with quicklime. He says the German soap was the purest, the fattest, and the best, and that the next in quality was the Gallic233. This account corresponds more exactly with the process used in Germany at present; whereas the French use mineral alkali, and instead of tallow, employ oil, which appears to be a later invention. Pliny in his description does not speak of quicklime; but as he mentions a mixture of goats’ tallow and quicklime a little before, it is probable that the use of the latter was then known at Rome. Gallic and German soap are often mentioned by later writers234, as well as by the Arabians, sometimes on account of their external use as a medicine, and sometimes on account of their use in washing clothes. The latter purpose is that for which soap is principally employed in modern times; but it does not seem to have been the cause of German soap being introduced at Rome. Washing there was the occupation of indigent scourers, who did not give themselves much trouble concerning foreign commodities. The German soap, with which, as Pliny tells us, the Germans coloured their hair red, was imported to Rome for the use of the fashionable Roman ladies and their gallants. There is no doubt that the pilæ Mattiacæ, which Martial recommends as a preventive of gray hair235; the caustica spuma with which the Germans dyed their hair236; and the Batavian froth or lather which the Romans employed for colouring theirs237, were German soap. It is probable that the Germans tinged it with those plants which were sent to Rome for dyeing the hair238; and according to the modern manner of speaking, it was more properly a kind of pomade than soap.
It appears that the Romans at first considered hair-soap as an ointment made from ashes; for we read in various passages of ancient authors, that the hair was dyed by means of ashes, or an ointment made of ashes and a certain kind of oil. It is however possible that they may have had such an ointment, which undoubtedly would be of a saponaceous nature, before they were acquainted with the German soap, or that they imitated the German pomade with different variations239.
As soap is everywhere used for washing at present, a question arises what substitutes were employed before it was invented. Those with which I am acquainted I shall mention and endeavour to illustrate. They are all still used, though not in general; and they are all of a