In the last century, some artists in Germany first fell upon the method of employing gold instead of iron, and of thereby making artificial rubies, which when they were well set could deceive the eye of a connoisseur, unless he tried them with a diamond or a file. The usual method was to dissolve the gold in aqua regia, and to precipitate it by a solution of tin, when it assumed the form of a purple-coloured powder. This substance, which must be mixed with the best frit, is called the precipitate of Cassius, gold-purple, or mineral-purple315.
This Cassius, from whom it takes its name, was called Andrew, and because both the father and the son had the same christian name, they have been often confounded with each other. The father was secretary to the duke of Schleswig, and is not known as a man of letters; but the son is celebrated as the inventor or preparer of the gold-purple, and of a bezoar-essence. He took the degree of doctor at Leyden, in 1632, practised physic at Hamburg, and was appointed physician in ordinary to the bishop of Lubec. As far as I know, he never published anything respecting his art; but this service was rendered to the public by his son, who was born at Hamburg, and resided as a physician at Lubec. He was the author of a well-known treatise, now exceedingly scarce, entitled Thoughts concerning that last and most perfect work of nature, and chief of metals, gold, its wonderful properties, generation, affections, effects, and fitness for the operations of art; illustrated by experiments316.
From this work, it will be easily understood why the author does not give himself out as the inventor of the gold-purple317, which he is commonly supposed to be, at which Lewis is much astonished. It is seen also by it that Leibnitz calls him improperly a physician at Hamburg, having probably confounded the father and son together318. Upon the whole, it is not proved that any of the Cassius’s was the inventor of the above precipitate, else it would certainly not have been omitted319 in this treatise; and mention of gold-purple is to be found in the works of several old chemists320.
Something of this kind has, doubtless, been meant by the old chemists, when they talk of red lions, the purple soul of gold, and the golden mantle; but what they wished to conceal under these metaphors, I am not able to conjecture. In the year 1606, when Libavius published his Alchemy, the art of making ruby-glass must have been unknown. He indeed quotes an old receipt for making rubies; and conjectures, that because the real stones of the same name are found in the neighbourhood of gold mines, they may have acquired their colour from that metal; and that by means of art, glass might be coloured by a solution of gold321. The later chemists, however, and particularly Achard, found no traces of gold, but of iron, in that precious stone322.
Neri, who lived almost at the same time as Libavius323, was better acquainted with the gold-purple, though his receipt is very defective. According to his directions, the gold solution must be evaporated, and the residue suffered to remain over the fire until it becomes of a purple colour. One may readily believe that this colour will be produced; but glass will scarcely be coloured equally through by this powder, and perhaps some of the gold particles will show themselves in it. Kunkel affirms, and not without reason, that something more is necessary to make rubies by means of gold; but he has not thought proper to tell us what it is324.
Glauber, who wrote his Philosophical Furnace325 about the middle of the seventeenth century, appears to have made several experiments with the gold-purple. He dissolved the metal in aqua regia; precipitated it by liquor of flint, and melted into glass the precipitate, which contained in it abundance of vitreous earth326.
None, however, in the seventeenth century, understood better the use and preparation of gold-purple than John Kunkel, who, after being ennobled by Charles XI., king of Sweden, assumed the name of Löwenstiern. He himself tells us, that he made artificial rubies in great abundance, and sold them by weight, at a high price. He says, he made for the elector of Cologne a cup of ruby-glass, weighing not less than twenty-four pounds, which was a full inch in thickness, and of an equally beautiful colour throughout. He employed himself most on this art after he engaged in the service of Frederic William, elector of Brandenburg, in the year 1679. At that time he was inspector of the glass-houses at Potsdam; and, in order that the art of making ruby-glass might be brought to perfection, the elector expended 1600 ducats. A cup with a cover, of this manufacture, is still preserved at Berlin. Kunkel, however, has nowhere given a full account of this art. He has only left in his works a few scattered remarks, which Lewis has collected327.
In the year 1684, earlier than Cassius, John Christian Orschal wrote his well-known work, Sol sine veste328, in which he treats, more intelligibly than any one before him, of the manner of making ruby-glass. He, however, confesses that Cassius first taught him to precipitate gold by means of tin; that Cassius traded in glass coloured with this precipitate, and that a good deal of coloured glass was then made at Freysingen, but that the art was kept very secret. As Orschal deserves that his fate should be better known, I shall here mention the following few particulars respecting him. About the year 1682 he was at Dresden, in the service of John Henry Rudolf, from whom he learnt many chemical processes, and particularly amalgamation, by which he gained money afterwards in Bohemia. After this he was employed at the mines in Hesse; but he brought great trouble upon himself by polygamy and other irregularities, and died in a monastery in Poland.
Christopher Grummet, who was Kunkel’s assistant, wrote, in opposition to Orschal, his known treatise, Sol non sine veste, which was printed at Rothenburg, in 1685329. In like manner, an anonymous author printed against Orschal, at Cologne, in 1684, another work, in duodecimo, entitled Apelles post tabulam observans maculas in Sole sine veste. The dispute, however, was not so much concerning the use of gold-purple, as the cause of the red colour, and the vitrification of gold.
It is worthy of remark, that Kunkel affirms he could give to glass a perfect ruby-red colour without gold; which Orschal and most chemists have however doubted. It is nevertheless said, that Krüger, who was inspector of the glass-houses at Potsdam, under Frederic William king of Prussia, discovered earlier the art of making ruby-glass without gold, and that a cup and cover of cut glass made in this manner is still preserved at Berlin.
Painting on glass and in enamel, and the preparation of coloured materials for mosaic work, may, in certain respects, be considered as branches of the art of colouring glass; and in all these a beautiful red is the most difficult, the dearest, and the scarcest. When the old master-pieces of painting on glass are examined, it is found either that the panes have on one side a transparent red varnish burnt into them, or that the pieces which are stained through and through, are thinner than those coloured in the other manner330. It is therefore extremely probable that the old artists, as they did not know how to give to thick pieces a beautiful transparent red colour, employed only iron, or manganese, which pigment, as already observed, easily becomes in a strong heat blackish and muddy331. Enamel-painters, however, were for a long time obliged to be contented with it. A red colour in mosaic work is attended with less difficulty, because no transparency, nay rather opacity, is required. At Rome those pieces are valued most which have the beautiful shining red colour of the finest sealing-wax. We are told by Ferber that such pieces were at one time made only by a man named Mathioli, and out of a kind of copper dross; at present (1792), there are several artists in that city who prepare these materials, but they are not able to give them a perfect high colour332.
[Of late years the interesting art of painting on