Liquid Crystals. Iam-Choon Khoo

velocity gradient tensor defined by Eq. (3.60).

      The viscosity coefficients γ₁ and γ₂ are related to the Leslie coefficient αs by [3]

      (3.68a)

      (3.68b)

      Consider the flow configuration depicted in Figure 3.11. Without the magnetic field and setting ϕ = 0, we have

      (3.69a)

      (3.69b)

      (3.69c)

      (3.69d)

      (3.69e)

      From Eq. (3.66) the viscous torque along the y‐direction is given by

      (3.70)

      In the steady state, from which the shear torque vanishes, a stable director axis orientation is induced by the flow with an angle θ_flow given by

      (3.71)

      For more complicated flow geometries, the director axis orientation will assume correspondingly complex profiles.

      

3.6. FIELD‐INDUCED DIRECTOR AXIS REORIENTATION EFFECTS

We now consider the process of director axis reorientation by an external static or low‐frequency field. Optical field effects are discussed in Chapter 6. The following examples will illustrate some of the important relationships among the various torques and dynamical effects discussed in the preceding sections. We will consider the magnetic field as it does not involve complicated local field effects and other electric phenomena (e.g. conduction). The electric field counterparts of the results obtained here for the magnetic field can be simply obtained by the replacement of Δχ ^m H ² by ΔεE ² (cf. Eqs. [3.26] and [3.29]).

      3.6.1. Field‐induced Reorientation Without Flow Coupling: Freedericksz Transition

The following example demonstrates how the viscosity coefficient γ₁ comes into play in field‐induced reorientational effects. Consider pure twist deformation caused by an externally applied field on a planar sample as depicted in Figure 3.12. Let θ denote the angle of deformation. The director axis is thus given by = (cos θ, sin θ, 0). From this and the preceding equations, the free energy (Eq. 3.4) and elastic torque (Eq. 3.13) are, respectively,

      (3.72a)

      and

      (3.72b)

Figure 3.12. Pure twist deformation induced by an external magnetic field H on a planar sample; there is no fluid motion.

      The viscous torque is given by

      (3.73)

      The torque exerted by the external field (applied perpendicular to the initial director axis), from Eq. (3.29), becomes

      (3.74)

      Hence, the torque balance τ equation gives

(3.75a) Скачать книгу